In a recent study, scientists have got closer to the answer—and their findings could reverberate long into the future. Not only is Roman concrete exponentially more durable than modern concrete, but it can also repair itself. Creating a modern equivalent that lasts longer than existing materials could reduce climate emissions and become a key component of resilient infrastructure, like seawalls. Currently, concrete is second only to water as the world’s most consumed material, and making it accounts for about 7 percent of global emissions. “We are dealing with extremely complex material,” says Admir Masic, a researcher at the Massachusetts Institute of Technology who led this new research on Roman concrete. “To kind of reverse-engineer or understand the original way these civilizations made this material is just a nightmare.” Until now, efforts to explain the longevity of Roman concrete have pointed to its use of volcanic tephra—the fragments of rock emitted in an eruption—mined in the Naples area and shipped to construction sites throughout the sprawling Roman empire. But Masic and his MIT colleagues, along with researchers from Harvard and laboratories in Italy and Switzerland, suggest another reason: heat. Using a number of different scanning techniques, they examined a sample from a city wall in Privernum, a 2,000-year-old archaeological site near Rome, focusing on millimeter-scale white chunks running through the sample, called lime clasts. These are not found in modern concrete. “Every wall made out of Roman concrete will have these inclusions,” Masic says, who in the past has looked at structures across Israel, North Africa, Italy, France, and Spain. Previously the lime clasts were thought to be a product of not mixing the concrete properly, Masic explains. But the team’s scanning revealed that the clasts were formed at extremely high temperatures, and are made from various forms of calcium carbonate. They contain a kind of calcium that Masic’s team theorized could heal cracks by reacting with water, creating a solution that recrystallizes in fissures to fill them in. That calcium, he says, could be the “missing link” explaining the material’s durability. The question, then, was where the necessary heat came from to make those clasts. It had been thought that Roman concrete was created by combining water with a calcium compound called slaked lime. But what if the Romans used lime in a more reactive form, called quicklime, Masic wondered. When mixed with water, quicklime reacts and produces heat. Patents have now been secured by MIT. Masic says a company will begin producing what he calls Roman-inspired concrete by year’s end. “Translating this knowledge of the ancient world into modern applications, I think that’s the next step,” he says. “These cracks are healed in two to three weeks using ingredients that are readily available and, most importantly, cheap.” Masic’s paper is the latest in a string of investigations into Roman concrete. Last year, he published research with Marie Jackson, a researcher at the University of Utah, that examined the 70-foot-tall tomb of first-century Roman noblewoman Caecilia Metella on the Appian Way, an ancient Roman road that runs across Italy. Their investigation revealed that the particular formation of Roman concrete used in the tomb interacts with rainwater and groundwater, becoming more resilient over time. And in earlier work, Jackson and her colleagues produced an exact replica of a similar concrete, used 1,900 years ago to build the Markets of Trajan in Rome, and developed an innovative fracture test to better measure its resilience, showing that it is far less brittle than modern concrete. Jackson also studied cores drilled from concrete in Roman harbors, determining that seawater moving through the concrete reacts with it to create new minerals that make the concrete more cohesive and resilient over time. Jackson has some concerns about Masic’s new paper, however. The sample it analyzed is undated, and it contains sand instead of the volcanic tephra typically used—the sample therefore isn’t representative of Roman concrete, she says. In response, Masic says his team plans to analyze other sites “to confirm our hypothesis” that the Romans used quicklime in their concrete recipe—known as hot mixing. Masic’s team also wants to look in more detail at the influence hot mixing had on how the Romans built their structures. So has Masic actually solved the mystery of how Roman concrete was made? “Who knows?” he says. “What I do know is we were able to translate some of these concepts into the real world. That’s what really excites me the most.” There’s the potential now to build better concrete, regardless of whether it is strictly “Roman” or not. This recipe and process were lost over a millennium ago. No similar concrete existed until Joseph Aspdin of Great Britain took out a patent in 1824 for a material produced from a mixture of limestone and clay. He called it Portland cement because it resembled Portland stone, a limestone used for building in England. Modern concrete is made from fragments of rock combined with Portland cement—a mixture of limestone, clay or shale, and other ingredients ground and burned at 1,450 degrees Celsius (2,642 degrees Fahrenheit). That process creates an enormous amount of greenhouse gas and leaves you with concrete that’s not durable, degrading sometimes in as little as 50 years, especially in marine environments. Roman concrete, in comparison, is strong, requiring no steel reinforcing it, unlike its modern counterpart. And it’s relatively cheap. On this front, Masic’s and Jackson’s labs are working with entrepreneurs interested in bringing their versions of Roman concrete to market. Jackson’s team, for instance, has collaborated with an industry partner to create a synthetic version of the volcanic tephra the Romans mined, because of the tremendous volume that will be needed. After years and years of pursuing an answer, Jackson is happy the quest is generating interest. “What’s really important and valuable is that the topic of Roman concrete is now in the media,” she says. “This is an incredibly sophisticated and complex material. The people who made it were so brilliant, and so precise in what they did, that it has taken us 15 years of work to decipher much of this. And we are humbled by how much more we have to learn.” Updated 2-3-2023 5:00 pm ET: This story was corrected to fully identify Joseph King and his professional experience.
